Earticle

ITO와 CNT를 적용한 전극을 코팅하여 제작한 대전입자형 전자종이 디스플레이 패널을 제작하여 내구성 및 전기광학적 특성을 비교한다. ITO 전극의 면저항은 10(ohm/sq.)이고 CNT 전극의 면저항은 300, 600, 1000(ohm/sq.)이며 내구성 측정을 위하여 물리적 충격 및 유연성 측정을 진행한다. ITO 전극의 경우 40회의 충격과 10㎜의 곡률 반지름에서부터 변화가 시작되나 CNT 전극에서는 변화가 측정되지 않는다. 입자 이동, 반사 율 및 응답 시간 측정에 필요한 구동 전압, 전계 등 전기광학 측정결과 CNT 전극은 ITO 전극과 유사한 결과를 얻었다.

Two types of charged particle-type electronic paper display panels with electrodes using ITO and CNT are fabricated to compare durability and electro-optical characteristics. The sheet resistance of the ITO electrode is 10 (ohm/sq.), and the sheet resistance of the CNT electrode is 300, 600, 1000 (ohm/sq.), and durability is carried out by impact and flexibility measurements. Variation in case of the ITO electrode begins at shocks of 40 times and curvature radius of 10 mm, and no change is observed in the CNT electrode. The driving voltage, electric field required for particle movement, reflectivity, and response time measurements show similar results for all ITO and CNT electrodes.

본 연구는 교사 전문적학습공동체를 유지하고 발전시키기 위하여, 실제적 효과를 정 확하게 측정하고 교사 전문적학습공동체의 방향을 제시하는데 목적이 있다. 이러한 목 적을 달성하기 위해 Kirkpatrick(1998) 평가모형을 기초로 초등학교 내 전문적학습공동 체에 융합교육(Science, Technology, Engineering, Art, & Mathematics: STEAM) 프로 그램을 과학적 측정도구인 전산화 신경 인지검사(Computerized Neuro-cognitive Function Test)를 활용하여 평가하였다. 1단계 반응평가에서 프로그램 만족도는 5점 리 커트 척도에서 4.32로 높은 수준의 만족도 결과를 보여 주었다. 2단계 학습평가에서는 정서지각능력, 인지통제능력, 암묵적 추론능력, 문제해결능력, 기억능력, 교수효능감을 측정하였다. 이중 교수효능감은 STEAM 교수효능감 도구를 이용하여 평가하였고, 나머 지 5가지 항목은 전산화 신경 인지검사로 평가하였다. 2단계 측정결과 STEAM 교수 효능감과 문제해결력 항목에서 통계적으로 유의한 향상이 있었다. 이 결과를 바탕으로 다음과 같은 결론을 제시하였다. 첫째, 전문적학습공동체는 교사들의 문제해결력 신장에 도움을 준다. 둘째, 전문적학습공동체는 관련 프로그램의 목표를 성취하는 데 도움을 주 고 교수 효능감 상승을 이끌어 낸다. 이를 바탕으로 교사 전문적학습공동체 학습방법과 프로그램 평가의 확장 등 교사 전문적학습공동체가 나아가야 할 방향성을 제시하였다.

In order to maintain and develop the teacher professional learning community (PLC), this study aimed to evaluate accurately the empirical outcomes of the PLC and present a direction for it. To achieve this purpose, outcomes of a STEAM program of the PLC in an elementary school were evaluated by using the computerized neuro-cognitive function test (CNT), a scientific measurement tool, based on the Kirkpatrick (1998) evaluation model. In the first-stage of evaluation (i.e., response), teacher satisfaction with the program was the high level of 4.32 on a five-point Likert scale. In the second-stage of evaluation (i.e., learning), we evaluated an improvement in six areas including emotional perception ability, cognitive control ability, implicit reasoning ability, problem-solving ability, memory ability, and teaching efficacy. The first five areas were measured with CNT, and the last one was measured with the STEAM teaching efficacy scale. As a result, we found that there were significant improvements in the problem-solving ability and STEAM teaching efficacy. Based on these results, conclusions were presented as follows: first, a PLC helps teachers improve their problem-solving skills; and second, the PLC is helpful to achieve the goals of relevant educational programs and improve teachers’ teaching efficacy. Finally, we provided a direction for PCL, including expansion of learning methods and program evaluation.

The characteristics of CNT-Polyamide composites were analyzed, that is, tensile strength, electrical resistivity, and thermal conductivity were measured according to the align length of CNT. There have been researches on the influence of aligned CNT to improve the mechanical and thermal characteristics in different areas including absorption and shielding of electromagnetic wave, thermal distribution or absorption, and high-strength of CNT. The aligned CNTs were synthesized by the ethylene gas with a CVD device preheated at 650℃. CNT-Polyamide composites were produced with the mixing of solution. CNT contents were controlled from 1phr to 50phr in the polyamide-ethanol solution, and blended with the 700W bar-type ultrasonic wave for 60 min.. And then CNT-polyamide were precipitated by CNT- polyamide-etnanol falling into the cold water. After dried 12 hours, CNT-polyamide composite were pressed at 150℃~180℃ with 400kgf to get the thickness of 1mm. As the conclusions, aligned CNT bundles were dispersed by cutting of CNT to the aligned direction because of polyamide properties. Tensile strength and electrical resistivity were improved to the increase of aligned length of CNT. Thermal conductivity was little affected by the align length of CNT.

This study is based on the screen printing method with heat resistant thin film as base material and development for expansion is proceeding. Therefore, it is convenient to be applicable to the installation and it will be possible to reduce the cost compared with the existing construction such as heat trace by 50% or more. As a result, it is possible to develop and commercialize the market for Polar ship, shipbuilding and offshore plants as it is possible to secure CNT(Carbon Nano Tube) based surface heating element and heating paste composition technology as a heating element material at a cryogenic temperature. It is expected that the efficiency will be great when this method is applied to other industries.

The effect of CNT diameters on properties of CNT-polyamide composites was investigated such as electrical conductivity, tensile strength and thermal conductivity. To get different diameter distributions of CNTs, several portions of Mo and Fe in Mo-Fe/MgO catalysts were synthesized by a combustion method at 600℃. And all CNTs growed at 900℃ with 3 SLM methane and 1 SLM hydrogen for 40min. Four kinds of CNTs with different diameter distributions, such as 1~3nm, 3~7nm, 7~13nm, and 10~30nm, were selected to make CNT-polyamide composites. Each composite was manufactured by a solution mixing using bar-type ultra-sonicator in the CNT portions from 1phr to 50 phr. And electrical conductivity, tensile strength, and thermal conductivity were measured. Three properties of CNT-polyamide composite, manufactured with 10nm diameter, were more excellent compared to other composites, with electrical conductivity 10 Ω at 7phr, thermal conductivity 2.4.W/mK at 40phr, tensile strength 60MPa at 30phr. CNTs with a diameter of 10nm were superior to other diameters for the multi-functional composite such as CNT-polyamide composites.

본 논문에서는 용액 기반의 탄소나노튜브(CNT: Carbon Nano-tube)를 전자기기의 전도성 소재로 사용하기 위하 여 쉽고 빠르게 형성하는 방법에 대해 연구하였다. 이를 위해 스핀 코팅 방법 및 아르곤 상압플라즈마 공정을 적용하여 글라 스 위에 CNT 박막 코팅을 진행하였다. 코팅 횟수에 따른 전기적, 물리적 특성 변화를 관찰하기 위하여 1회부터 5회까지 동 일한 방법으로 형성된 샘플을 제작하였고, 각 샘플에 대해 표면 형상, 반사도, 투과도, 흡수율 및 표면 저항을 측정하였다. 현 미경을 이용하여 관찰했을 때 횟수가 늘어날 때 글라스 상에 검은 형상이 더 잘 관찰되며, 특히 스핀코팅에 의해 가운데 영역 이 더 검게 관찰되는 것을 알 수 있다. 코팅 수가 증가함에 따라 측정 파장의 전 영역에서 투과도는 감소, 반사도 및 흡수율은 증가하였다. 또한, 파장이 감소함에 따라 투과율은 감소, 반사도 및 흡수율은 증가한다. 전기적인 특성의 경우, 2번 코팅했을 때 전도도가 상당히 향상됨을 확인할 수 있었으며, 추가 코팅에 의해서 전도도 감소가 관찰되지만, 큰 변화를 보이지는 않았 다. 결론적으로 CNT를 투명전극으로 대체하기 위해서는 반사도 및 전기전도도를 함께 고려하여 코팅 횟수를 고려해야 하며, 2회가 최적임을 알 수 있다.

In this paper, a simple method of forming a solution-based carbon nanotube (CNT) for use as a conductive material for electronic devices was studied. The CNT thin film coating was performed on the glass by applying the spin coating method and the argon atmospheric pressure plasma process. In order to observe changes in electrical and physical properties according to the number of coatings, samples formed in the same manner from times 1 to 5 were prepared, and surface shape, reflectance, transmittance, absorbance, and sheet resistance were measured for each sample. As the number of coatings increased, the transmittance decreased, and the reflectance and absorptivity increased in the entire measurement wavelength range. Also, as the wavelength decreases, the transmittance decreases, and the reflectance and absorption increase. In the case of electrical properties, it was confirmed that the conductivity was significantly improved when the second coating was applied. In conclusion, in order to replace CNT with a transparent electrode, it is necessary to consider the number of coatings in consideration of reflectivity and electrical conductivity together, and it can be seen that 2 times is optimal.

This experimental focus to characterize luminescence properties related to CNT (Carbon Nano Tube) element dispersedly implanted in ZnS-based phosphor thin film panel fabricated by a screen printing method. More specifically FE-SEM measurements, L-V(Luminescence vs. Voltage) and photo luminescence were carried out to determine an optimum value of CNT concentration and film thickness for the thin film structure of CNTーZnS:(Cu, Al) by the screen printing method. We confirmed that an optimum value of CNT concentration in the ZnS:(Cu, Al) film panel is about 0.75 wt% resulting that the electric conductivity is 1.6 times higher than that of pure CNT sample and showing that the luminescence intensity is increasing until the optimum concentration. Clearly, CNT is presenting in the luminescence process providing a pathway for the creation of hot electron and a channel for the electron-hole recombination but overly inserted CNT may hinder to produce the hot electron for making an avalanching process. In case of the overly doped CNT 1.0 wt% in the ZnS-based phosphor, the luminescence intensity is decreasing although the electric conductivity is exponentially increasing. Based on these results, we realized that hot electron occurred by the external electric field or exciton arose by the external photon source are reduced dramatically over the critical value of CNT concentration because CNT element provide various isolated residues in the composites of ZnS based phosphor rather than pathway or channel for the D-A(Donnor to Acceptor) pair transition or the radiative recombination of electron-hole.