Earticle

In this study, we compared of control characteristics at two-stroke marine diesel engine by MAN B&W. It was found that MC and ME type of engine largely divide fuel injection & exhaust valve actuator by cam-shaft controlled and electro-hydraulic controlled. Computer based type of engine ME-B type is only operated exhaust valve by driving camshaft, the fuel injection system is fuel oil booster and ELFI valve by Electro-hydraulic. ME-C type is composed of a multi-way valve or FIVA valve. Therefore fuel injection system and exhaust valve system is operated by Electro-hydraulic. ME type engine was shown that the optimization of the combustion process can be achieved for any load on the engine by Electro-hydraulic control system according to the computer based.

본 연구에서는 솔-젤 공정을 도입하여 나노크기의 산화네오디뮴 제조를 위한 기초연구를 수행하였다. 본 연구조건에서 솔-젤 공정은 반응 초기에 킬레이트화 반응과 가수분해 반응이 완료되며, 또한 가수분해의 진행에 따라 축합중합반응은 유기산 형성 축합중합 보다는 물 형성 축합중합반응이 더 우세하였다. 솔-젤 반응의 진행을 위해서는 네오디뮴 이온과 젤화 보조재인 유기산의 몰 비는 1 : 2가 적절하였다. 솔-젤 공정을 통하여 얻어진 젤 분말의 소성 시 소성온도가 증가함에 따라 생성되는 산화네오디뮴의 결정도가 향상되었다. 젤화 보조재인 유기산의 종류는 산화네오디뮴의 형태에 중요한 역할을 하며, citric acid의 경우에는 소성온도에 무관하게 스폰지 형태를 가졌으며, malonic acid의 경우에는 900 이하에서는 스폰지 형태를 그리고 1000 이상에서는 미세입자로 세분화되었다. 따라서 솔-젤 공정에 의하여 나노 입자의 산화네오디뮴 제조가 가능할 것으로 사료된다.

In this study, a preparation of nano-size neodymium oxide by sol-gel process was carried out. Chelation and hydrolysis was finished in early stage of sol-gel reaction, and the water-forming condensation was more superior than the organic acid-forming condensation. Mole ratio of neodymium and organic acid, 1 : 2 was appropriate for sol-gel process. When gel powder prepared by sol-gel process was calcinated to obtain neodymium oxide, crystallity of neodymium oxide increased with increasing of calcination temperature. The kind of organic acid as gelation agent played important role in the shape of neodymium oxide. In the case of citric acid, neodymium oxide had sponge type which had no relation with calcination temperature. But in the case of malonic acid, neodymium oxide had sponge type under 900 of calcination temperature, and fractionized nano-size particlesabove 1000 . It was possible to prepare nano-size neodymium oxide by sol-gel process.

전기로 제강 공정에서 분진은 제강생산량의 1 ~ 2%가 발생하고 있으며, 분진 중에는 유가금속인 Zn과 Fe가 20 ~ 30% 정도 함유되어 있다. 전기로 배가스에 포함된 분진은 전기로 출구 덕트를 빠져나와 배가스를 완전연소하기 위한 연소탑과 냉각을 위한 냉각탑을 거쳐 Bag filter에 포집된다. 연소탑 하단에서 비중 차이에 의해 포집되는 분진은 전체 발생량의 15%에 해당하며 기존 Bag filter 분진보다 고가로 위탁처리 되고 있다. 본 연구는 연소탑 하단에 포집되는 분진의 유가금속 분리 회수에 대한 연구로서, 전기로 조업 시점과 분진의 입도에 따른 성분을 분석하여 유가금속의 함량 차이를 비교하였다. 본 연구 결과 전기로 조업 시점에 따른영향 보다는 입도에 따라 Zn과 Fe의 함량에 큰 차이를 보였다.

During steelmaking on EAF, 1 ~ 2% of dust is generated. EAF Dust contains 20 ~ 30% of Zn and Fe. Dust contained in Offgas is passed through combustion tower and cooling tower, and then captured in bag filter. About 15 wt.% of dust is dropped at the bottom of Combustion tower by its specific gravity, which was also carried out to recycle company with more higher charge than Bag filter dust. This study is focused on the combustion tower dust, and seperation as a function of operation period and particle size. As a result, Zn and Fe content of dust is more affected by size factor than operation period.

Due to the use of time, machine wear degree, coal and other reasons, the original set parameters of the boiler have been unable to meet the control requirements, therefore using a large amount of data to build a real model of the power station based on the neural network, therefore, to establish a boiler combustion optimization neural network model by using of the power plant operating data. According to the shortcomings on RBF neural networks traditional training methods with slow convergence speed, easy to fall into the local minimum. Firstly, this paper Set the model to single input and single output system as the research object, optimize neural network by the particle swarm optimization algorithm. Finally, this modeling method is expanded to the multiple input multiple output system field. Use MATLAB to establish the simulation model and the simulation research, the simulation results show that improved method for combustion boiler system efficiency has been significantly improved, combustion efficiency of the entire system reached 94%, the accuracy of the system model was significantly better than ordinary neural network, system training error controls in less than 5% .We can see that the improved method is feasible and effective.

It is necessary to understand the combustion process and cycle-by-cycle variation in combustion to improve the engine stability and consequently to improve the fuel economy and exhaust emissions. The pressure related parameters instead of mass fraction burned were compared for the effect of initial combustion pressures on the following combustion and the analysis of cycle-by-cycle variation in combustion for two pen injected SI engines. The correlation between IMEP and pressures at referenced crank angles showed almost the same trends for equivalence ratios, but the different mixture preparations indicated different tendency. The dependency of IMEP on pressure at the referenced crank angles increases as the mixture becomes leaner for both engines. The mixture distribution in the combustion chamber was varied with the coolant temperature and intake valve deactivation due to the evaporation of fuel and air motion. The correlation between pressure related parameters were also compared for the coolant temperatures and air motion.

자동차엔진의 연소과정에 상사하는 밀폐정적연소실을 주연소실과 대향 2개 부연소실로 분할하고 오리피스로 연결하였다. 이때 부연소실로부터 주연소실로 분출하는 대향분출염 연소에 의한 질소산화물 배출저감특성을 연소방식, 연소실형상 그리고 연료종류를 변경한 수종의 실험으로 조사하였다. 질소산화물농도, 연소실 최고압력, 화염전파과정의 고속도슐리렌사진 가시화를 수행한 결과, 대향분출염 연소방식을 도입하연 연소실의 중앙부공간이 상대적으로 넓은 경우에 고부하운전과 동시에 질소산화물의 배출량도 저감할 수 있었다. 그러나 연료의 종류는 질소산화물생성에 매우 영향이 적었다.

Ultrafine NiO/YSZ (Yttria Stabilized Zirconia) powders were made by using a glycine nitrate process which is used as anode material for solid oxide fuel cells. The specific surface areas of synthesized NiO/YSZ powders were examined with controlling pH of a precursor solution and the content of glycine. The binding of glycine with metal nitrates occurring in the precursor solution was analyzed by using FTIR. The characteristics of synthesized powders were examined with X-ray diffraction(XRD) Brunauer Emmett Teller with N2 absorption. scanning electron microscopy (SEM). and transmission electron microscopy (TEM). Ultrafine NiO/YSZ powders of 15-18 m2/g were obtained through GNP when the content of glycine was controlled to 1 or 2 times the stoichiometric ratio in the precursor solutions. Strongly acid precursor solution increased the specific surface area of the synthesized powders. This is suggested to be the increased binding of metal nitrates and glycine under a strong acid solution of pH=0.5 that lets glycine consist of mainly the amine group of {{{{ { NH}`_{3 } ^{+ } }}. After sintering and reducing treatment of NiO/YSZ powders synthesized by GNP the Ni/YSZ pellet showed ideal microstructure where very fine Ni particles of 3-5 ${\mu}{\textrm}{m}$ were distributed uniformly and fine pore around Ni metal particles was formed. leading to anincrease of the triple phase boundary among gas Ni and YSZ.

Lanthanides such as La, Gd and Ce have recognized as elements of high level radioactive wastes immobilized by forming solid solution with $CaTiO_3$. For easy forming solid solution between $CaTiO_3$and lanthanides, the combustion synthesis process was applied and the powder characteristics and sinterability were investigated. The proper selection of the type and the composition of fuels are important to get the crystalline solid solution of $CaTiO_3$and lanthanides. When glycine or the mixtures of urea and citric acid with stoichiometric composition was used as a fuel, the solid solution of $CaTiO_3$with $La_2O_3$or $Gd_2O_3$or $CeO_2$was produced very well by the combustion process. The combustion synthesized powder seemed to have a good sinterability with the linear shrinkage of more than 25% up to $1500^{\circ}C$, while that of the solid state reacted powder was less than 10% at the same condition.

Nanoparticle powders of zinc stannate indate spinel (Zn2SnO4) were prepared with a single step process. The first nano-oxides of ZnO and SnO2 were obtained by microwave-assisted combustion of aqueous solution of metal nitrates (as the oxidizer) and urea (as fuel). This method is rapid, effective, cheap and convenient. In this paper, different combinations of fuel to oxidant ratio was used to prepare Zn2SnO4 nanoparticle and its effect on structural, morphological and optical characteristics were investigated using powder X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectra meter and UV-Vis absorbance spectroscopy, respectively. The structural parameters were calculated from XRD pattern which confirmed the spinel structure of Zn2SnO4. The SEM investigations evidenced the presence of homogeneous distribution of spherical nanoparticles.

In this study, a 3D CFD analysis method for the combustion process was established for a low calorific value syngas-diesel dual-fuel engine operating under very lean fuel-air mixture condition. Also, the accuracy of computational analysis was evaluated by comparing the experimental results with the computed ones. To simulate the combustion for the dual-fuel engine, a new dual-fuel chemical kinetics set was used that was constituted by merging two verified chemical kinetic sets: n-heptane (173 species) for diesel and Gri-mech 3.0 (53 species) for syngas. For dual-fuel mode operations, the early stage of combustion was dominated by the fuel burning inside or near the spray plume. After which, the flame propagated into the syngas in the piston bowl and then proceeded toward the syngas in the squish zone. With the baseline injection system and piston shape, a significant amount of unburned syngas was discharged. To solve this problem, effects of the injection parameters and piston shape on combustion characteristics were analyzed by calculation. The change in injection variables toward increasing the spray plume volume or the penetration length were effective to cause fast burning in the vicinity of TDC by widening the spatial distribution of diesel acting as a seed of auto-ignition. As a result, the unburned syngas fraction was reduced. Changing the piston shape with the shallow depth of the piston bowl and 20% squish area ratio had a significant effect on the combustion pattern and lessened the unburned syngas fraction by half.

We produced cylindrical porous TiNi bodies by Self-propagating High-temperature Synthesis (SHS) process, varying the heating schedule prior to ignition of a loose preform compact made from (Ti+Ni) powder mixture. To investigate the effect of the heating schedule on the behaviour of combustion wave propagation and the structure of porous TiNi shape-memory alloy (SMA) body, change of temperature in the compact during SHS process was measured as a function of time and used for determining combustion temperature and combustion wave velocity. Microstructure of produced porous TiNi SMA body was observed and the results were discussed with the combustion characteristics. From the results it was concluded that the final average pore size could be controlled either by the combustion wave velocity or by the average temperature of the preform compact prior to ignition.

The dispersed nanocrystallite particles of ZnFe2O4 have been synthesized by sol-gel auto-combustion with the aid of ultrasonic irradiation methods using different fuel additives of glycine, urea and thiourea. The ratios of fuel- to- nitrates were maintained variously at 1.2 : 1, 2 : 1, and 3 : 1. The results revealed that, the difference in the phase composition formed are mainly attributed to the combustion process. In turn, different fuel additives exert a direct influence in the combustion reaction on the formation of a homogeneous gel, the formation of a good complex with metal cations and release chemical energy; as well as, showed that, the crystallite size of Zn ferrite powders is affected by the compositional ratios of fuel?to-nitrates. High fuel/ oxidant ratios increase the particle size and may enhance dopant segregation. The studies on the composition of phases, crystallite sizes, and morphology of the powder ferrite formed were investigated by X-Ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The results demonstrated that, the average crystal sizes distribution obtained were in the range 11-38 nm for all compositions.

The performance of a direct-injection type diesel engine often depends on the strength of swirl or squish, shape of combustion chamber, the number of nozzle holes, etc. This is of course because the combustion in the cylinder was affected by the mixture formation process. In this paper, combustion process of biodiesel fuel was studied by employing the piston which has several grooves with inclined plane on the piston crown to generate swirl during the compression stroke in the cylinder in order to improve the atomization of high viscosity fuel such as biodiesel fuel and toroidal type piston generally used in high speed diesel engine. To take a photograph of flame, single cylinder, four stroke diesel engine was remodeled into two stroke visible engine and high speed video camera was used. The results obtained are summarized as follows; (1) In the case of toroidal piston, when biodiesel fuel was supplied to plunger type injection system which has very low injection pressure as compared with common-rail injection system, the flame propagation speed was slowed and the maximum combustion pressure became lower. These phenomena became further aggravated as the fuel viscosity gets higher. (2) In the case of swirl groove piston, early stage of combustion such as rapid ignition timing and flame propagation was activated by intensifying the air flow in the cylinder. (3) Combustion process of biodiesel fuel was improved by the reason mentioned in paragraph (2) above. Consequently, the swirl grooves would also function to improve the combustion of high viscosity fuel.

본 연구에서는 폐 2,4,6-트리나이트로톨루엔(2, 4, 6-trinitrotoluene, TNT)의 친환경 연소처리 공정을 개발하고, 이를 이용한 연소조건 최적화를 통한 연소 잔유물 중 유기물 최소화에 대한 기초연구의 데이터를 제시하였다. TNT는 자체적으로 완전연소가 어려운 물질로 외부에서 열을 가해주는 조건인 버너의 가열시간 변화, 추진제(가연물)와 혼합하여 소각, 연소 후 잔유물에 대한 2차 고온처리의 방법으로 실시하였다. 실험결과 잔유물 내 유기물 함량 감소를 확인하였으며, 각 방법별 최소 7 ~ 10%의 유기물 함량을 나타내었다. 최적의 연소시간 조건에서 폐TNT의 연소 잔유물 중 유기물 함량은 1차 소각로만 사용한 경우 9% 수준을 보였으며, 동시에 폐가스의 환경친화성도 폐가스 실시간 분석에서 확인 되었다. 1차 소각이후 소각 잔유물을 외부의 전기로를 이용하여 추가적으로 고온처리 처리할 경우 유기물 함량을 2% 정도 추가적으로 감소시킬 수 있었다. 추진제가 포함된 연소공정에서는 추진제 함량에 따른 잔유물 중 유기물의 함량 감소가 가능함이 나타나 다양한 TNT 폐기물을 처리할 수 있음을 알 수 있었다. 폐기물관리법에서 소각 후 잔유물 내 유기물 함량 15% 미만을 충족하는 수치이다.

In this study, an eco-friendly combustion process of waste 2,4,6-trinitrotoluene (TNT: 2,4,6-trinitrotoluene) was developed, and fundamental data for the quantity of the organic matter in the final combustion residues is presented. Because complete combustion of TNT is not possible theoretically, the combustion process was optimized to reduce organic matter content in the combustion residue by performing measures such as heating time changes, addition of propellant material, and after treatment using a high-temp electrical furnace. From the results, it was confirmed that the organic matter content in the residue could be decreased to 7 ~ 10% with each method. The quantity of the organic matter could be minimized by optimizing the combustion conditions of the process. With only a combustion time increase, the amount of organic matter in the combustion residues was measured at about 9 wt%. The environmental friendliness of the final exhaust gas was also confirmed by real time gas component analyses. In addition, the organic contents could be reduced by a further 2 wt% by applying an additional heat treatment using an external electric furnace after the first incineration treatment. In the combustion process of propellant added waste TNT, it was found that various TNT wastes could be treated using the same eco-friendly protocols because the organic content in the residue decreased in accordance with the amount of propellant. The amount of the organic matter content produced by all these methods fulfilled the requirements under the Waste Management Act.

The autoignition and combustion messes of a diesel spray are numerically studied. To simulate the autoignition and the combustion process in a diesel spray, the wave instability breakup model, the Shell ignition model, arid the mod- eddy breakup model are implemented in the KIVA-II code. The coupling mechanism between fluid mechanics and chemical reaction associated with autoignition is discussed in detail. Numerical results indicate that the mixing process along the edges of spray jet has a crucial role for autoignition and combustion process. We also investigate effects of injection pressure and concentration of $\textrm{O}_2$ and $\textrm{CO}_2$ on the autoignition process in the diesel/EGR environment.

여기에서,고온공기류 덕트(duct)를 사용해서 실린더 내에 있어서의 분무연소 를 단순화하고저 하는 시도가 본 연구이다.

디젤 엔진의 연비와 배기를 개선하고자 하는 노력으로 다운사이징이 강화되고 있다. 이에 따라 엔진의 사이즈는 작아지고, 엔진 연소실 내 온도와 압력은 상승하는 추세이다. 따라서 높은 온도와 압력 조건에서 연료 분무의 발달과정과 연소과정 연구가 매우 중요하다. 본 연구에서는 디젤 엔진 연소실의 고온 고압 환경을 벤치에서 모사해줄 수 있는 정적 연소실을 개발하였다. 정적 연소실은 예혼합기를 연소시켜 순간적으로 온도와 압력을 급격하게 상승시킨 다음, 주변으로의 열전달에 의해 온도와 압력이 감소할 때 시험 목표조건인 온도와 압력 조건에 다다르면, 연료 분사기에 신호를 인가하여 연료분무를 개시하며 쿼츠 창을 통하여 연료 분무를 가시화 한다. 이 때, 정적 연소실 내에 연료 분무가 이루어지는 영역의 온도를 정확히 측정하여 정확한 시험 조건을 형성해야 한다. 본 연구에서는 고속으로 온도를 측정할 수 있는 열전대를 직접 개발 및 제작하여 연소실 내 시공간적 온도분포를 측정하였다. 측정 결과, 전체 체적 온도보다 연료 분무가 개시되는 중심 공간의 온도가 더 높게 나타났으며, 이는 연소실 벽면으로의 열전달 때문임을 확인하였다. 또한 횡방향으로의 온도 편차는 약 10%이내 수준이었으나, 종방향으로 온도편차가 최대 15%수준으로 나타났고 이는 부력으로 인한 고온의 연소가스의 상승효과 때문으로 판단되었다.

Downsizing is widely applied to diesel engines in order to improve fuel efficiency and reduce exhaust emissions. Engine sizes are becoming smaller but pressure and temperature inside combustion chambers are increasing. Therefore, research for fuel spray under high pressure and temperature conditions is important. A constant volume chamber which simulates high temperature and pressure likely to be found in diesel engines was developed in this study. Pressure and temperature were increased abruptly because of ignition of the pre-mixture in the constant volume chamber. Then pressure and temperature were gradually decreased due to the heat loss through the chamber wall. Fuel spray occurred when temperature and pressure were reached at the target condition. In this experiment, the temperature condition should be exactly defined to understand the relation between fuel evaporation and ambient temperature. A fast response thermocouple was developed and used to measure the temporal and spatial temperature distribution during the combustion process inside the combustion chamber. In the results, the core temperature was slightly higher than the bulk temperature calculated by the gas equation. Ed-note: do you want to say 'ideal gas equation'? This was attributed to the heat transfer loss through the chamber wall. The vertical temperature deviation was higher than the horizontal temperature deviation by 5% which resulted from the buoyancy effect.

The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in the high-pressure engine conditions. The high-pressure vaporization model is developed to realistically simulate the spray dynamics and vaporization characteristics in high-pressure and high-temperature environment. The interaction between chemistry and turbulence is treated by employing the Representative Interactive Flamelet (RIF) Model. The detailed chemistry of 114 elementary steps and 44 chemical species is adopted for the n-heptane/air reaction. In order to account for the spatial inhomogeneity of the scalar dissipation rate, the multiple RIFs are introduced. Numerical results indicate that the RIF approach together with the high-pressure vaporization model successfully predicts the ignition delay time and location as well as the essential features of a spray ignition and combustion processes.

The effects of turbulent flow characteristics affected on early combustion process in methanol-air mixture have been stuied in a constant volume vessel. Instantaneous flow velocity turbulent intensity and turbulent scale were investigated in order to analyze the turbulent flow characteristics Experiments were made under different turbulent intensity and turbulent scale. A comparison of the turbulent flow characteristics on flame kernel volume and flame kernel volume variation ratio is also presented.

In the combustion treatment of explosive gases with a high heating value such as $H_2$ and $NH_3$ used in semiconductor and chemical processes, the heat recovery modeling and exergy analysis of the process using the Aspen Plus simulator and its thermodynamic data were performed to examine the recovery of high temperature thermal energy. The heat recovery process was analyzed through this process modeling while the exergy results clearly confirmed that the rigorous reaction mainly occurs in the condenser and the chamber. In addition, the process modeling demonstrated that approximately 95% of the exergy is destructed on the basis of the exergies injected and the exergy being exhausted. Using the exergy technique, which can quantitatively analyze the energy, we could understand the energy flow in the process and confirm that our heat recovery process was efficiently designed.