2019 International Symposium of Institute of Forest Science (2019.09)바로가기
페이지
pp.122-122
저자
Eun-Ah Lee, Song-Yi Han, Chan-Woo Park, Ji-Soo Park, Gu-Joong Kwon, Seok-Ju Kim, Seung-Hwan Lee
언어
영어(ENG)
URL
https://www.earticle.net/Article/A450363
원문정보
초록
영어
In this study, lignin was isolated by ionic liquid (IL) treatment from lignocellulosic biomass (Quercus mongolica), and the characteristics of the obtained lignin were investigated. The wood powder was loaded in ILs ([EMIM]Ac, [AMIM]Cl, [BMIM]Cl, [HMIM]Cl) to a 15wt% concentration, and then the reaction was conducted at 140 °C for 2h. The reactant was vacuum-filtrated, and the residue was washed using an acetone/distilled water (1/1, v/v) solution. The filtrate was evaporated using an evaporator to remove the acetone in the filtrate. Next, the filtrate was added in distilled water (2L), and then the pH of the filtrate was adjusted to pH 2 using a HCl solution to precipitate IL-isolated lignin (ILL). The yields of ILL in [EMIM]Ac, [AMIM]Cl, [BMIM]Cl and [HMIM]Cl were 5.28%, 1.66%, 1.55%, and 1.52%, respectively. As the reaction temperature in [EMIM]Ac was increased, the yield of ILL and soluble fraction were increased. Molecular weights of ILLs were 4388, 2657, 2260, and 2660(g/mol) for [EMIM]Ac, [AMIM]Cl, [BMIM]Cl and [HMIM]Cl, respectively. The hydroxyl group content of the ILL by [EMIM]Ac was 2.58 mmol/g.
키워드
Ionic liquidLignin extractionBiorefinery
저자
Eun-Ah Lee [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Song-Yi Han [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Chan-Woo Park [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Ji-Soo Park [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Gu-Joong Kwon [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Seok-Ju Kim [ Wood Chemistry division, Forest Products Department, National Institute of Forest Science, Seoul, 02455, Republic of Korea ]
Seung-Hwan Lee [ Division of Forest Material Science & Engineering College of Forest and Environmental Sciences, Kangwon National University ]
Corresponding Author