Earticle

초록

영어

A special emphasis is devoted to initiating, developing and combining new physical properties within the heterometallic systems enclosing cores of three different spin-carriers. The rational inclusion of 3d and/or 4f cations within the same molecular entity could generate new categories of heterotrimetallic complexes which possesses the special properties on photo magnets, luminescent or chiral compounds or with combined properties, namely magneto-luminescence or magneto-chirality. These new molecular materials open large perspectives to developing molecular “prototypes” for revolutionary optical, high-storage devices or in quantum computing. In this research the synthesis and characterization of Heterotrimetallic complexes of the type [RuCl(PPh3)(L2)](where L=bidentate Schiff base ligand of ferrocenylthiosemicarbazone) was attempted by reacting [RuCl(PPh3)3] with bidentate Schiff base ligand of ferrocenylthiosemicarbazide. During this synthesis the complexes obtained have been characterized by Elemental analysis, IR and Electronic spectroscopy. This confirms Heterotrimetallic Fe(II)-Ru(III)-Fe(II) complex with PPh3. This complex finds its use as precursor for some carcinogenic drug and it paves the way to the area of superamolecular material research.

목차

Abstract
 1. Introduction
 2. Methodology
  2.1. Preparation of Acetyl Ferrocene
  2.2. Preparation of Bidentate Schiff Base Ligands
  2.3. Preparation of 1- Acetylferrocene thiosemicarbozone (HAFTSC)
  2.4. Preparation of 1- Acetylferrocene -4 Phenylthiosemicarbozone(HAFPTSC)
  2.5. Preparation of trichlorotris (triphenylphosphine) ruthenium(III) RuCl3(PPh3)3]
  2.6. Preparation of new Ruthenium(III) complexes:- [RuCl(PPh3)(FTSC)2]
  2.7. [RuCl(PPh3)(FPTSC)2]
 3. Results and Discussions
 References

키워드

저자

• Sivahari R. [ Department of Chemistry, Kumaraguru College of Technology, Coimbatore – 49 ]
• Syed Shabudeen P.S. [ Department of Chemistry, Kumaraguru College of Technology, Coimbatore – 49 ]

참고문헌

발행기관

간행물

표지보기 관심저널 등록

• 간행물명

  International Journal of Bio-Science and Bio-Technology

• 간기

  격월간

• pISSN

  2233-7849

• 수록기간

  2009~2016

• 등재여부

  SCOPUS

• 십진분류

  KDC 505 DDC 605