Earticle

본 연구는 세 종류의 서로 다른 규사와 강모래의 조합이 알칼리-활성화 슬래그(AASC) 시멘트의 압축강도와 건조수축 특성에 주는 영향에 대한 것이다. 모래의 특성은 알칼리 활성화 시멘트의 특성에 중요한 영향을 미친다. 세 종류의 규사 (S1, S2 그리고 S3)와 강모래 (RS)를 사용하였다. 또한 세 종류의 혼합 모래에대해 실험을 수행하였다. 첫 번째 시리즈 (S1)는 강모래(RS)와 규사1 (SS1)을, 두 번째 시리즈 (S2)는 강모래(RS)와 규사2 (SS2)를, 세 번째 시리즈(S3)는 강모래 (RS)와 규사3 (SS3)을 서로 다른 비율로 혼합하였다. 그 결과 혼합 모래는 AASC 모르타르의 특성에 특이할만한 영향을 주는 것으로 나타났다. 모래의 입자크기와 혼합율의 관계에 따른 압축강도와 건조수축은 혼합된 모래의 조립률(FM)과 상대 표면적이 충분히 고려되어야 한다. 모래의 종류와 혼합비율은 AASC 모르타르의 배합 설계에 중요하게 고려되어야 할 요소이다.

In this paper, the performance of alkali-activated slag cement (AASC) is assessed in terms of compressive strength and drying shrinkage, using three different types of silica sand and river sand. The sand type has an important influence on the properties of AASC mortar. Three silica sands (SS1, SS2 and SS3) and river sand (RS) were considered. Three series of blended sands have been tested. A first series (S1) with RS and SS1, a second series (S2) with RS and SS2 and third series (S3) with RS and SS3 with a different blended ratios. The result shows a very significant influence of the blended sand on the AASC mortar properties. The compressive strength and drying shrinkage related with the particle sizes and blended ratios of sands are investigated considering blended sand properties like fineness modulus (FM) and relative specific surface. The type and blended ratio of sand seems to have very significant and important consequences for the mix design of the AASC mortar.

건축물에서의 화재 발생은 인명피해, 구조물 피해 등 재해적 요소를 많이 포함하고 있으며, 가연물의 증가에 따라 화재 발생빈도수와 피해 규모는 점차 증대하는 추세이다. 특히 강재로 구성되는 기둥부재와 보부재의 고온 시 내력의 급격한 감소는 구조물의 붕괴와 같은 매우 위험한 상황에 도달될 수 있으므로 화재 시 강구조 건축물의 구조 안전성 확보를 위해서는 적용 강재의 신뢰성 있는 고온 물성자료가 매우 중요하다. 따라서 본 연구에서는 강구조 건축물에서 많이 활용되는 용접구조용 강재인 SM 400강재를 대상으로 고온 시 항복강도, 탄성계수를 측정하여 내력평가에 활용할 수 있는 실험식을 제시하고, 화재 시의 온도평가와 응력 계산에 요구되는 열전도율과 열팽창계수 등의 열적 특성의 자료를 제시한다. 또한 일반 구조용 강재인 SS 400과의 고온 특성을 비교, 평가함으로써 고온에서의 내력 특성을 확인한다.

Recently, the risk of fire outbreak is going up because of newly developed combustible materials are intended to apply more. Especially the steel framed structure can lose its load-bearing capacity when it is exposed to higher temperature condition such as a fire. So the pre-evaluation of fire resistance of the structure is very essential that the mechanical properties of yield strength and elastic modulus and thermal properties such as conductivity and linear expansion be required. To get the databases for SM 400 or welding structural steels at high temperature, various temperature conditions were used for deriving the yield strength, elastic modulus, linear expansion, and conductivity and the results were compared to those of SS 400, ordinary structural steel, respectively.

치과 교정치료를 위하여 스테인리스 선재가 널리 사용되고 있다. 그러나 내식성이 우수한 스테인리스강 선재가 복합적인 구강환경에서 부식되어 구강조직에 과민반응 또는 이상반응이 발생되고 있다. 이러한 문제를 보완하기 위하여 본 연구에서는 초내식성의 듀플렉스 스테인리스 선재를 교정용 선재로 제시하고 자 한다. DSS선재의 교정용 선재로 제시하기 위하여 기계적 강도와 생물학적 안정성을 평가하였다. 기계적 강도는 상용 교정용 SS선재와 6종의 열처리(실온($28^{\circ}C$), $500^{\circ}C$, $600^{\circ}C$, $700^{\circ}C$, $800^{\circ}C$, $900^{\circ}C$)를 실시한 DSS선재를 이용하여 인장강도시험을 실시하였다. 그리고 최적의 강도를 가지는 열처리 조건에서 제작된 DSS선재를 이용하여 굽힘 모멘트 시험을 실시하여 최대 응력과 탄성계수를 산출하였다. 그리고 생물학적 안정성 평가를 위하여 세포성장률 시험을 실시하였다. 선재를 이용하여 금속용출배지를 만들어 세포를 배양 후 세포성장률을 관찰하였다. 기계적 강도 평가 결과 SS선재($8.17\times10^4\;N/mm^2$)와 DSS500($8.05\times10^4\;N/mm^2$)선재가 유사한 기계적 강도를 가졌다(p=0.05). 생물학적 안전성 평가 결과 세포 독성이 없는 것으로 나타났다(p=0.05). 따라서 본 연구에 제시한 초내식성의 듀플렉스 스테인리스 선재가 교정용 선재로 사용이 가능한 것으로 판단된다.

The stainless steel wire is extensively used for the orthodontic treatment. But, the stainless steel wire that has commonly superior corrosion resistance has caused hypersensitive reaction or allergy as side effects because of corrosion in the oral environment. For improving the problem of corrosion, we was evaluated the suitability of the duplex stainless steel(DSS) as orthodontic wire through this study. The DSS wire was evaluated the mechanical strength and bio-stability for suitability and bio-compatibility as orthodontic wire. In this work, the DSS and stainless steel(SS) as common use of medical grade were prepared for the tensile strength test. The DSS wire were treated by heat. and Temperature conditions of the heat treatment were $28^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, $700^{\circ}C$, $800^{\circ}C$, $900^{\circ}C$, respectively. And the DSS wires that treated by heat on the optimum temperature condition were conducted the bending moment test and calculated the S-Max value and the modulus of elasticity. For evaluating the bio stability, each materials were conducted in vitro test for measuring the cell survival rate. The most interesting results was that the tensile strength test of SS wire($8.17\times10^4\;N/mm^2$) and DSS wire($8.05\times10^4\;N/mm^2$) that treated at $500^{\circ}C$ by heat were similar in mechanical strength. In the bio-stability study, the DSS has no cytotoxicity (p=0.05) Thus, we could make a conclusion that the duplex stainless steel wire has vastly superior corrosion resistance was suitable as orthodontic wire.

화재와 같은 고열환경에서 강구조 건축물의 구조적 붕괴 예측 및 화재피해 건축물의 안전진단 그리고 보수보강을 위해서는 고온에서의 항복강도와 탄성계수 등과 같은 특성치가 반드시 요구된다. 따라서 본 연구에서는 강구조 건축물의 주요 구조부에 적용되는 주요 강종인 일반 구조용 SS 400과 용접 구조용 SM 490을 대상으로 상온에서 $100^{\circ}C$ 간격으로 $900^{\circ}C$까지 고온인장시험을 통하여 0.2% 옵?V 항복강도, 1% 옵?V 항복강도, 인장강도 및 탄성계수 등을 측정하였다.

The mechanical properties such as 0.2% and 1% offset proof strength and elastic modulus are essential for a structural steel structure when the structure would be evaluated and designed to identify the performance of the structural stability exposed to fire condition. To obtain the mechanical properties for the structural steels at high temperature which are consisted of ordinary and marine ones, the tensile tests at various high temperatures had been conducted with two kinds of specimen of general structural steel SS 400 and welded steel SM 490 at the range of room temperature to $900^{\circ}C$ at interval of $100^{\circ}C$.

Pet coke (PC) and sewage sludge (SS) have been separately used as admixtures into clayey raw materials for ceramic manufacturing by extrusion and sintering. Thermal analysis of the clay mixtures incorporating 6% of either PC or SS shows a significant shift of the solidification temperature to lower temperatures. The bending strength-in terms of modulus of rupture (MOR)-of the ceramic specimens produced does not change appreciably up to 6% content in PC or SS, indicating that the manufactured clay-based ceramics are able to tolerate low percentages of these admixtures. The specimen open porosity increases and the thermal conductivity decreases by increasing the admixture percentage, while both thermal conductivity and MOR increase with increasing sintering temperature. The results indicate that the utilization of PC and SS in ceramic manufacturing processes may lead to changes in processing parameters, to energy savings and to materials with improved thermal insulating properties.

Studies have been carried out to investigate the effect of the chemical structure of reactive urethane acrylate prepolymers and diluents on the properties of the Uv - curable polyure-thane acrylates for secondary optical fiber coating. Several urethane acrylate prepolymers were prepared from 4,4'- dicyclohexylmethane diisocynate(HMDI) and butandiol(BD) /poly(ethylene butane adiphate diol)(SS)polyol and 2-hydroxyethyl acrylate(HEA) with dibutyl tin dilulate as a catalyst. The UV - curable secondary coating material for optical fiber was formulated from the prepolymer, photoinitiator and one of two different diluents such as tetraethyleneglycol diacrylate(TEGDA) and trimethylol propane triacrylate(TMPTA). By dynamic mechanical thermal analysis, the storage modulus of the coating material film was found to increase with increasing BD and TMPTA contents. The maximum tan 8 peak for the coating materials prepared in this study was in the range of 70 and 90˚C. The maximum tan 8 and loss modulus peaks shifted to higher temperature with increasing BD content. The tensile strength and modulus increased with the increase of the number of functional group of diluent. The higher strength and modulus are due to the high content of hard segment and crosshnking by multifunctional diluent, respecti-vely. The desirable BD content is in the range of 5Omol% % and 6Omol %, and TMPTA content is about 30wt % for secondary coating material of high modulus.

The effects of annealing on the physical properties of poly(1-oxotrimethylene) (POTM) fibers were investigated in terms of draw ratio (DR). Annealing increased the degree of orientation with increasing DR. Analysis of wide angle X-ray diffraction patterns and Raman spectra suggested that annealing caused crystal structure transition from the ${\beta}$-form to the ${\alpha}$-form, which had a denser and more perfect crystal structure. The ${\beta}$-form and ${\alpha}$-form crystals were favorably formed for as-spun fibers and DR 13 fibers, respectively. In the fiber of DR 4, a combination of both ${\alpha}$- and ${\beta}$-form crystals was observed. Once the fiber was melted, no melt crystallization took place during cooling. Infrared spectra revealed that the melting process changed the chemical composition of POTM fibers by thermal decomposition, resulting in disappearance of the melt crystallization. In the stress-strain (SS) curve, the as-spun fibers exhibited yield behavior and a plateau region, while the drawn fibers gave a typical SS curve of brittle material without a plateau region. POTM fibers of DR 13 exhibited a significant increase in tensile modulus compared with as-spun and DR 4 fibers.