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Forest inventory is a commercial term meaning the preparation of detailed descriptive list of articles with number, quantity and value of each item included. Forest inventory deals with the measurement of trees and stands, the estimation of their volume, growth prediction, biomass, carbon stocks and the description tree characteristics, as well as the land upon which they are growing. National Forest Inventory Center (NFIC) in Korea conducts national forest inventory every 5 years to obtain accurate baseline data for national forest policy. The permanent sample plot data used in were collected by NFI. The objective of this study was to develop methods for quantifying forest resources at national scale based on 5th National Forest Inventory (NFI) data in Korea. Forest land area decreased from 6.44 to 6.38 million ha between 1997 and 2007, continuing a slight downward trend in area beginning in the late 1990s. However forest resources of the Korea have continued improving in general condition and quality, as measured by increased average size and volume of trees. Growing-stock volume of the Korea increased from 17 to 123.79 cubic meter per ha between 1976 and 2007. The biomass in Korea was estimated to be 153.81 tons per hectare and carbon stocks in Korea was estimated to be 84.36 tons per hectare by NFI data. This information is important for government officials, public administration, the private business sector, and the researcher. Forest Inventory should be implemented in a way to be able to monitor and assess the forests continuously.