Earticle

초록

영어

Synthetic dyes typically contain impurities formed during the manufacturing process, including intermediates, by-products and colored impurities called as subsidiary colors. Among synthetic dyes, azo dyes were synthesized similarly by diazotization and coupling reactions, which can produce similar subsidiary colors. Since azo dyes and their subsidiary colors are known to possess carcinogenic and other toxic properties, appropriate control measures need to be required. In this study, we developed an analytical method for the simultaneous determination of 10 subsidiary colors derived from azo dyes using high performance chromatography-diode array detector (HPLC-DAD), and monitored subsidiary colors and Food Yellow No. 5 (sunset yellow FCF) in commercially available raw materials and beverages. The developed method can successfully detect subsidiary colors at low level of 0.012―0.068 mg/L, and show acceptable performances for accuracy and precision. As percentage contents of subsidiary colors in commercial beverages containing Food Yellow No. 5 were lower than or comparable to those in raw materials, most of subsidiary colors were not intentionally added to beverages but are presumed to be produced from Food Yellow No. 5. We also found that the percentage contents of subsidiary colors in commercial food colorants satisfied the national and international ‘Specifications and Standards for Food Additives’.

목차

Abstract
Ⅰ. 서론
Ⅱ. 재료 및 방법
1. 시약 및 재료
2. 시료 전처리
3. 분석기기 및 조
4. 분석법 검증
5. 모니터링
Ⅲ. 결과 및 고찰
1. HPLC-DAD 분석조건 최적화
2. 분석법 검증
3. 모니터링 결과
4. 국내･외 기준과의 비교
Ⅳ. 결론
Ⅴ. 사사

키워드

저자

• 권정은 [ Jeongeun Kwon | 국립과학수사연구원 독성학과 감정관 ]
• 이아영 [ Ayoung Lee | 국립과학수사연구원 독성학과 감정관 ]
• 박미정 [ Meejung Park | 국립과학수사연구원 독성학과 감정관 ]
• 김형주 [ Hyung Joo Kim | 국립과학수사연구원 독성학과 감정관 ] Corresponding Author

참고문헌

발행기관

간행물

표지보기 관심저널 등록

• 간행물명

  한국법과학회지 [Korean Journal of Forensic Science]

• 간기

  반년간

• pISSN

  1598-0715

• 수록기간

  2000~2026

• 등재여부

  KCI 등재

• 십진분류

  KDC 367 DDC 347