A metalloporphyrin-based coordination framework material was synthesized by the reaction of Sn(OH)2(TPyP) complex (TPyP = 5,10,15,20-tetrakis(4-pyridyl)porphyrinato dianion) with Ag(OTs) (OTs = p -toluenesulfonato monoanion), and thoroughly characterized using various analytic techniques including X-ray crystallography. The X-ray crystal structural analysis revealed that peripheral coordination of pyridyl nitrogen with Ag(I) ions creates a two-dimensional network. This framework contains two different types of pore channels, with approximate edge dimensions of 21.6 × 15.2 Å and 13.7 × 7.11 Å, respectively.
목차
Abstract 1. Introduction 2. Materials and Methods 2.1. Synthesis of [Sn(OTs)2(TPyP)]3(AgOTs)4ž18(H2O) (1) 2.2. Synthesis of Sn(OTs)2(TPyP) (2) 2.3. X-ray crystallography 3. Results and Discussion 4. Conclusions Acknowledgments References
Nirmal Kumar Shee [ School of Chemical Materials Engineering, Kumoh National Institute of Technology ]
Jonghoon Jeon [ Department of Applied Chemistry, Kumoh National Institute of Technology ]
Hee-Joon Kim [ School of Chemical Materials Engineering, Kumoh National Institute of Technology/ Department of Applied Chemistry, Kumoh National Institute of Technology ]
Corresponding Author
조선대학교 기초과학연구원 [The Natural Science Research Institute of Chosun]
설립연도
2008
분야
자연과학>자연과학일반
소개
본 연구원은 기초과학을 진흥하기 위한 연구·교육 및 그 보급을 목적으로 한다. 이 목적을 달성하기 위하여 다음 각 호의 사업을 수행한다.
1. 기초과학 제 분야에 관한 조사와 연구
2. 기초과학에 관한 학술행사(학술대회, 학술세미나, 심포지엄, 초청강연회 등) 개최
3. 학문후속세대 및 일반인을 위한 기초과학 교육
4. 기관지『조선자연과학논문지』 발간
5. 『자연과학연구총서』, 『자연과학번역총서』 등 단행본 발간
6. 기타 본 연구원의 목적과 관련된 사업
간행물
간행물명
통합자연과학논문집(구 조선자연과학논문집) [Journal of Integrative Natural Science]