부패 시료 헤드스페이스 기체의 전기 아크방전 전처리를 통한 수소 제거 및 헬륨 검출 향상 연구
Enhancing Detection of Helium in Putrefied Samples via Electric Arc Preprocessing for Hydrogen Removal
Helium is widely utilized colorless and odorless inert gas, which poses a risk of hypoxia-induced asphyxiation when encountered in high concentrations, as it diminishes the partial pressure of oxygen during respiration. Accurate detection of helium from autopsy sample is essential for forensic investigations to ascertain the cause of death in suspected cases of helium asphyxiation. Conventionally, Gas Chromatography with a Thermal Conductivity Detector (GC-TCD) is employed for headspace gas analysis of autopsy samples. Nonetheless, the efficacy of this method is often compromised by helium's low reactivity and the minimal residual presence in samples, further complicated by hydrogen interference resulting from putrefaction. This study introduces a novel preprocessing technique that utilizes an electric arc to initiate a reaction with oxygen, effectively eliminating hydrogen from the headspace gas and thus enhancing the detection of helium. Experimental validation revealed that a 5-minute preprocessing period could remove 95% of hydrogen, while a 10-minute treatment achieved a 97% reduction. The successful detection of helium in putrefied autopsy samples underscores the effectiveness of this method, offering a promising approach to improve helium detection in forensic contexts.
목차
Abstract Ⅰ. 서론 Ⅱ. 사례 보고 Ⅲ. 재료 및 방법 Ⅳ. 결과 및 고찰 Ⅴ. 결론 Ⅶ. 참고문헌
법과학 분야는 사회정의 구현에 있어 크나큰 가치가 있음에도 불구하고 우리나라에서는 이 분야에 대한 인식이 미흡하여 선진 외국에 비해 침체되어 있는 실정이다. 이에 우리나라에서도 법과학 분야와 관련 있는 학계, 연구기관, 수사기관 등 유관 단체들로 구성된 한국 법과학회를 창립하여 이 분야를 활성화 시켜 과학수사를 한층 더 발전시키기 위함을 목적으로 한다.