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Research Article

A Preliminary Study on the Roles of Fe Content and Neoformed Ca-rich Minerals in the Coloration of Ceramic Glazes

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  • 발행기관
    한국문화유산보존과학회(구 한국문화재보존과학회) 바로가기
  • 간행물
    보존과학회지 KCI 등재 바로가기
  • 통권
    제36권 제4호 (2020.08)바로가기
  • 페이지
    pp.275-283
  • 저자
    Min Hye Lee, Min Su Han, Ji Hye Kim
  • 언어
    영어(ENG)
  • URL
    https://www.earticle.net/Article/A380670

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초록

영어
Iron oxides are the essential coloring oxides in traditional ceramic glazes. However, when Fe is involved in the coloration in the form of ions or colloids in glazes with low Fe content, it is difficult to identify the iron oxide phases. Generally, in many these glazes, Ca-rich minerals are observed by X-ray diffraction (XRD) or microscopic images, owing to their devitrification by the high Ca content. This study attempts to elucidate the correlation between the crystalline structure and coloration in the glazes while mainly focusing on neoformed Ca-rich minerals and Fe content. An experimental firing was carried out to produce tree ash glazes, with pine tree ash and Buyeo feldspar. In the case of oxidation glazes, the scanning electron microscopy (SEM) images and XRD patterns did not exhibit any Ca-rich crystals, and all the visible light reflectance spectra lines exhibited a similar shape. In contrast, the reduction glazes divided into blue glazes and other colored glazes according to the shapes of their reflectance spectra. It was confirmed that the influence of Ca-rich minerals on the glaze color was more pronounced than the blue color of the reduction glazes when the Ca and feldspar contents were sufficiently high and low, respectively, to form wollastonite. As the Ca content increased and the elemental composition of the reduction glazes changed, the neoformation of the Ca-rich minerals, such as wollastonite, anorthite, diopside, and akermanite was sequentially observed.

목차

ABSTRACT
1. INTRODUCTION
2. MATERIALS AND METHODS
2.1. Materials
2.2. Methods
3. RESULTS
3.1. Analysis results for the glaze raw materials
3.2. Analysis results for the fired specimens
4. DISCUSSION AND CONCLUSION
ACKNOWLEDGEMENTS
REFERENCES

키워드

Iron oxides Colorant Wollastonite Anorthite Diopside Akermanite

저자

  • Min Hye Lee [ Department of Heritage Conservation and Restoration, Graduate School of Cultural Heritage, Korea National University of Cultural Heritage, Buyeo 33115, Korea ]
  • Min Su Han [ Department of Heritage Conservation and Restoration, Graduate School of Cultural Heritage, Korea National University of Cultural Heritage, Buyeo 33115, Korea ] Corresponding Author
  • Ji Hye Kim [ Department of Heritage Conservation and Restoration, Graduate School of Cultural Heritage, Korea National University of Cultural Heritage, Buyeo 33115, Korea ]

참고문헌

자료제공 : 네이버학술정보

간행물 정보

발행기관

  • 발행기관명
    한국문화유산보존과학회(구 한국문화재보존과학회) [The Korea Society of Conservation Science for Cultural Heritage]
  • 설립연도
    2003
  • 분야
    자연과학>자연과학일반
  • 소개
    본 법인은 문화재 과학적 보존에 관한 제반 학술적 연구 발전 보급을 위하여 문화재 보존기술 개발과 수리 및 복원에 관한 방법을 연구함으로서 문화재의 보존 및 계승에 기여함을 그 목적으로 한다.

간행물

  • 간행물명
    보존과학회지 [Journal of Conservation Science]
  • 간기
    연5회
  • pISSN
    1225-5459
  • eISSN
    2287-9781
  • 수록기간
    2003~2026
  • 등재여부
    KCI 등재
  • 십진분류
    KDC 602 DDC 700

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