We characterized the smelting process and smelting furnace through scanning electron microscopy-energy dispersive spectroscopy, wavelength dispersive X-ray fluorescence, X-ray diffraction, and raman micro-spectroscopy with 13 relics including slags and furnace walls excavated from square-shaped building sites and pits of the Three Kingdoms site at the Ungyo site section I. Our results revealed that the principal components were FeO and SiO2; and CuO, PbO, and ZnO were contained in small quantities. Furthermore, fayalite, magnetite, augite, copper, and cuprite were found. High contents of FeO or SiO2 components seem to have been added to form fayalite to remove gangue in the smelting process. The relatively low content of S detected in the copper prills suggests that roasting was performed well. Cristobalite and mullite, which are minerals that indicate high-temperature found in the furnace wall, show that the smelting temperature was higher than 1,250°C. The findings of this study show a high possibility that the Wanju Ungyo site is smelting remains of copper ores, which are nonferrous metals, rather than iron. Various smelting byproducts excavated in this area in the future will help us better understand the copper smelting process that may have been performed since ancient times.
목차
ABSTRACT 1. INTRODUCTION 2. STATUS OF RESEARCH OBJECTS 2.1. Remains 3. ANALYSIS OBJECTS AND METHOD 3.1. Analysis objects 3.2. Analysis method 3.3. Analysis result 4. DISCUSSION AND CONCLUSION REFERENCES
키워드
Copper smeltingSlagFurnace wallUngyo siteCopper
저자
Su Jeong Lee [ Chungnam Cultural Heritage Association, Yesan 32432, Korea ]
Nam Chul Cho [ Department of Cultural Heritage Conservation Science, Kongju University, Gongju 32588, Korea ]
Corresponding Author
Byoung Sun Kang [ Honam Cultural Property Research Center, Damyang 57371, Korea ]