Phthalocyanine derivatives have perhaps received more attention than any other class of dyes as sensitizers for photodynamic therapy and most favoured are the aluminium and zinc derivatives. Photoinduced electron transfer in donor-acceptor molecules has been extensively studied, in particular for covalently linked dyads in solution as model systems of natural photosynthesis to harvest efficiently solar energy. In this study, the characterizations for immobilization o f R. sphaeroides on two phthalocyanines were evaluated. There are two solvent for phthalocyanines, water and SDS. In order to determine electron reaction of cell bound phthalocyanines, we are confirmed cyclic voltammetry measurement. R. sphaeroides bound ZnPc in water solvent and CuPc in SDS solvent were shown active electron reactions. It was correlated with the amount of cell bound phthalocyanine by photo-luminescence at 683nm for emission and at 600nm for excitation. In addition, electron reactions of R. sphaeroides on phthalocyanines were increased for 10 days storage period. Phthalocyanines as electron donoron on R. sphaeroids can apply for improving photosynthetic efficiency.
키워드
PhthalocyaninesZnPcCuPcR. sphaeroides
저자
Hyun Jeong LEE [ Graduate School of Semiconductor and Chemical Engineering, Chonbuk National University, 664-14 Duckjin-dong, 1Ga Duckjin-Gu Jeonju 561-756. ]
Yang-Hoon KIM [ Department of Microbiology, Chungbuk National University, 410 Sungbong-Ro, Heungduk-Gu, Cheongju 361-763. ]
Jiho MIN [ Graduate School of Semiconductor and Chemical Engineering, Chonbuk National University. ]
한국생물공학회 [The Korean Society for Biotechnology and Bioengineering]
설립연도
1984
분야
공학>생물공학
소개
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