Earticle

초록

영어

There has been an increased interest in the use of vegetable oils due to low cost and large quantity production. Vegetable oils can be used as raw materials to prepare eco-friendly biodegradable polymer material. In this study, novel crosslinked polymer networks based on vegetable oils were prepared by UV photopolymerization and their mechanical properties were evaluated. The raw material used was acrylated epoxidized soybean oil (AESO.) 2,5-furan dicarboxylic acid (FDCA) was identified by the US Department of Energy as one of 12 priority chemicals for establishing the green chemistry industry of the future. It is often synthesized from 5-hydroxymethylfurfural, which in turn can be obtained from D-fructose. In this study, 2,5-furan diacrylate was synthesized from 2,5-furan dimethanol, which can be derived from FDCA to use as crosslinking agent to form crosslinked polymer networks by UV-initiated free-radical polymerization with AESO. The synthesis of acrylate derivatives was confirmed using FT-IR and 1H-NMR spectroscopic techniques. The composition of reaction mixture (the ratio of AESO to crosslinking agent) and the type of crosslinking agent (monoacrylate and diacrylate) were changed to obtain crosslinked polymer networks with various mechanical properties.

키워드

저자

• Na Ri Jang [ Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea. ]
• Beom Soo Kim [ Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea. ]

참고문헌

발행기관

간행물

표지보기 관심저널 등록

• 간행물명

  한국생물공학회 학술대회

• 간기

  반년간

• 수록기간

  1985~2013

• 십진분류

  KDC 476 DDC 576